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Characterization

Structure, Chemistry, Optical and Dielectric Properties of a New Pyrophosphate: LiGaP2O7

8:25 AM–8:45 AM Feb 24, 2020 (US - Pacific)

San Diego Convention Ctr - Theater A-6

Description

Mallesham Bandi1, Ron Broner2, Samuel Arredondo1, Ramana Chintalapalle1; 1University of Texas at El Paso, 2University of California, Santa Barbara

Phosphate based materials are extensively studied in recent years due to their fascinating physical properties and potential technological applications including; solid state lasers, electrochemical energy devices, catalysis, luminescence. In this work, we report on the structural, optical and dielectric properties of a novel material, LiGaP2O7, synthesized using conventional solid-state chemical reaction. Calcination of sample was carried at different temperatures with intermediate grinding. X-ray diffraction of calcined sample confirms that sample calcined at 650 °C for 8 h exhibits phase purity without any secondary phases. The physical, chemical and electronic property analyses made and results obtained are compared with well-studied LiFeP2O7, which is an excellent candidate for lithium ion batteries. Finally, we made an attempt to establish a correlation between crystal structure, phase, microstructure, optical and electrical properties of LiGaP2O7.
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